Hydrogen-Abstraction/Acetylene-Addition Exposed

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Hydrogen-Abstraction/Acetylene-Addition Exposed.

Polycyclic aromatic hydrocarbons (PAHs) are omnipresent in the interstellar medium (ISM) and also in carbonaceous meteorites (CM) such as Murchison. However, the basic reaction routes leading to the formation of even the simplest PAH-naphthalene (C10 H8 )-via the hydrogen-abstraction/acetylene-addition (HACA) mechanism still remain ambiguous. Here, by revealing the uncharted fundamental chemist...

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ژورنال

عنوان ژورنال: Angewandte Chemie

سال: 2016

ISSN: 0044-8249

DOI: 10.1002/ange.201607509